Multiphoton ionization processes in HCl studied by photoelectron spectroscopy
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions
- Vol. 86 (11) , 2035-2041
- https://doi.org/10.1039/ft9908602035
Abstract
A (2 + 1) REMPI–PES study of HCl has been carried out in the two-photon energy region between 77 000 and 85 500 cm–1. The observed 1Δ(2), 3Δ(2), 3Π(1) and 3Σ–(0+) states are characterized as Rydberg states. The one-photon ionization of the B 1Σ+ state has been shown to be dominated by indirect processes involving competition between electronic autoionization and dissociation via superexcited states.Keywords
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