Mixed-valence coinage metal clusters with 1,1-thioperthio ligands. Syntheses and molecular structures of the copper and gold [Cu4L3]2-, [Cu5L4]-, and [AuCu4L4]- anions (L = 1,1-dicarbo-tert-butoxyethylene-2,2-thioperthiolate). A geometrically-locked, charge-separated valence state in the [Cu5L4]- anion
- 1 December 1993
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 115 (24) , 11271-11278
- https://doi.org/10.1021/ja00077a028
Abstract
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