Heterobinuclear Oxo-Bridged Complexes. III. CrIIIOmoV Compounds—Synthesis and Magnetic Properties
- 1 January 1992
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 45 (5) , 889-896
- https://doi.org/10.1071/ch9920889
Abstract
Redox reactions between CrIVO (P) (P is a porphyrin dianion ) and MoIVO( dtc )2 ( dtc is adithiocarbamate anion) result in the formation of oxo -bridged Cr111OMOV compounds. The variation of magnetic susceptibility with temperature to 25 K shows evidence for strong antiferromagnetic coupling for the pyrrolidyldithiocarbamate complex with J = -300 cm-1.Keywords
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