Stereoselective cis-Addition of Aromatic C−H Bonds to Alkynes Catalyzed by Dinuclear Palladium Complexes
- 13 September 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (40) , 12102-12103
- https://doi.org/10.1021/ja0375075
Abstract
Reactions of alkynes with arenes proceeded in the presence of dinuclear palladium complexes and trialkylboranes to yield alkyne hydroarylation products with high stereoselectivity. In the reactions of monosubstituted benzenes, meta and para products were formed in statistical ratios, while no ortho isomers were detected.Keywords
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