Raman difference spectra of solutions of electrolytes in formamide
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 71, 709-713
- https://doi.org/10.1039/f29757100709
Abstract
A phase-sensitive detection method for recording Raman difference spectra is described. The method has been applied to concentrated solutions of LiNO3, LiCl, and NaNO3 in formamide in order to determine the separate effects of anion and cation changes on the solvent spectrum. The Raman data are interpreted in terms of the ion solvation effects, and interionic association is demonstrated.Keywords
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