A New Approach to Protonics in the H-bonded Charge-Transfer Crystals
- 1 January 1989
- journal article
- future projects-and-development
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics
- Vol. 171 (1) , 343-355
- https://doi.org/10.1080/00268948908065806
Abstract
Our recent study of the proton transfer in the double-well potential of the H-bonded charge-transfer (CT) crystals is introduced together with several other related topics. Special attention is focused on our investigation into the control of the dynamical motion of protons by using the excess a-electron effect on the hydrogen bonding in the CT-interaction system, which provides useful information in the design of a new molecular function using the H-bonded CT complexes. In this process, optical transitions enhanced by the dynamical motion of protons has been identified as the proton-linked super-CT transitions.Keywords
This publication has 28 references indexed in Scilit:
- Cooperative Phenomena Associated with Electron and Proton Transfer in Quinhydrone Charge-Transfer CrystalPhysical Review Letters, 1988
- Possible relevance of soliton solutions to superconductivityNature, 1987
- Optical reflectivity spectra of the mixed-stack organic charge-transfer crystal tetrathiafulvalene-p-chloranil under hydrostatic pressurePhysical Review B, 1987
- Electric conductivity and phase diagram of a mixed-stack charge-transfer crystal: Tetrathiafulvalene-p-chloranilPhysical Review B, 1987
- Soliton Formation at the Neutral-to-Ionic Phase Transition in the Mixed-Stack Charge-Transfer Crystal Tetrathiafulvalene -- ChloranilPhysical Review Letters, 1984
- Anomalous Nature of Neutral-to-Ionic Phase Transition in Tetrathiafulvalene-ChloranilPhysical Review Letters, 1981
- On the theory of the structural phase transition in squaric acidPhysica Status Solidi (b), 1976
- A Molecular Orbital Study on the Effects of Excess Charges at the Donor and Acceptor Atoms on the Hydrogen BondBulletin of the Chemical Society of Japan, 1974
- Electronic Spectra and Electrical Resistivities of the Molecular Complexes of Benzidine and Its DerivativesBulletin of the Chemical Society of Japan, 1971
- Effect of Hydrogen Bonding on the Electrical Conductivity of Organic SolidsThe Journal of Chemical Physics, 1967