Photochemistry of Aromatic Olefins. II. Intramolecular Energy Transfer in 5-Phenyl-2-pentene
- 15 October 1970
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 53 (8) , 2993-2999
- https://doi.org/10.1063/1.1674439
Abstract
Intramolecular energy transfer in 5‐phenyl‐2‐pentene has been studied monitoring cis–transisomerization of solutions of the compound in cyclohexane. The intersystem crossover yield of the phenyl moiety is calculated to be 0.66 or less. The rate of intramolecular energy transfer is found to be much faster than that of intermolecular energy transfer in the concentration range studied.Keywords
This publication has 18 references indexed in Scilit:
- Photochemical reactions. III. Intramolecular triplet energy transferJournal of the American Chemical Society, 1970
- Photochemistry of Aromatic Olefins. I. Photochemical cis–trans Isomerization of 1-Phenyl-2-buteneThe Journal of Chemical Physics, 1970
- Temperature dependence of the phosphorescent lifetime of benzene, alkylbenzenes, and alkyl phenyl ethers between 4.2 and 100.deg.KThe Journal of Physical Chemistry, 1970
- Temperature dependence of the phosphorescence lifetime of benzene and n-alkylbenzenes between 4.2 and 100.deg.KThe Journal of Physical Chemistry, 1969
- Benzene Photosensitizationin Liquid PhaseThe Journal of the Society of Chemical Industry, Japan, 1969
- Conjugated Dienes as Quenchers for Excited Singlet States of Aromatic Hydrocarbons1Journal of the American Chemical Society, 1966
- Triplet state yields for benzene and benzene-d 6 in the vapour phaseTransactions of the Faraday Society, 1966
- Diffusion studies in viscous mediaProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1965
- Short Wave-Length Cut-Off Filters for the Ultraviolet*Journal of the Optical Society of America, 1948
- The photo-oxidation of hydrocarbon solutionsTransactions of the Faraday Society, 1939