Simple halogenonitrosyl anions of iron
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 16,p. 1525-1527
- https://doi.org/10.1039/dt9760001525
Abstract
The complex [N(PPh3)2][Fe(CO)3(NO)] reacts with alkyl halides to afford [N(PPh3)2][FeX2(NO)2](X = Cl, Br, or I) and with halogens to afford [N(PPh3)2][FeX3(NO)](X = Cl or Br) and [N(PPh3)2][FeI2(NO)2]. The relations between the two sets of paramagnetic anions, their reactivity, and their magnetic and e.s.r. spectral properties are discussed.Keywords
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