A NOVEL METHOD FOR THE SYNTHESIS OF 2,2,2-TRIBROMOETHANOLS FROM ALDEHYDES AND CARBONTETRABROMIDE IN THE PRESENCE OF STANNOUS FLUORIDE —A SYNTHESIS OF DIACETYL-d-ERYTHRONOLACTONE—
- 5 October 1981
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 10 (10) , 1505-1508
- https://doi.org/10.1246/cl.1981.1505
Abstract
In the presence of stannous fluoride, 2,2,2-tribromoethanols are conveniently prepared from aldehydes and carbontetrabromide under a mild reaction condition. The reaction is efficiently applied to the synthesis of 2,3-diacetyl-D-erythronolactone starting from 2,3-O-isopropylidene-D-glyceraldehyde.Keywords
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