Methyl migration by epoxide cleavage. The effect of carbonium ion stabilisation by a neighbouring double bond on the direction of migration on cleavage of 9β,11β-epoxy-4,4-dimethylandrost-5-ene-3,17-dione
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1271
- https://doi.org/10.1039/c29700001271
Abstract
The stabilisation of a developing cationic centre by an adjacent double bond has been found to direct the migration of the 10-methyl group to C-9 on cleavage of 9β,11β-epoxy-4,4-dimethylandrost-5-ene-3,17-dione.Keywords
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