A CONVENIENT METHOD FOR THE MILD REDUCTIVE DEBROMINATION OF α-BROMO KETONES AND OF vic-DIBROMOALKANES WITH STANNOUS CHLORIDE/DIISOBUTYLALUMINUM HYDRIDE

5 December 1984

journal article
research article
Published by Oxford University Press (OUP) in Chemistry Letters

Vol. 13 (12) , 2069-2070
https://doi.org/10.1246/cl.1984.2069

Abstract

A new reducing agent prepared by the treatment of stannous chloride with diisobutylaluminum hydride was shown to be effective for debrominations of α-bromo ketones to ketones and of vic-dibromoalkanes to the corresponding alkenes under mild conditions.

Keywords

CHLORIDE/DIISOBUTYLALUMINUM HYDRIDE
CONVENIENT METHOD
REDUCTIVE DEBROMINATION
VIC DIBROMOALKANES
STANNOUS CHLORIDE/DIISOBUTYLALUMINUM
BROMO KETONES

This publication has 2 references indexed in Scilit:

Dehalogenation of .alpha.-chloro and .alpha.-bromo ketones. Use of sodium O,O-diethyl phosphorotelluroate
The Journal of Organic Chemistry, 1982
Synthesis of d,l-muscone from cyclododecanone
Journal of the American Chemical Society, 1975