Chemistry of the Podocarpaceae. L. Conversion of 12-Hydroxypodocarpa-8,11,13-trien-19-oic acid (podocarpic acid) into 19-Hydroxypodocarp-8(14)-en-13-one
- 1 January 1974
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 27 (11) , 2413-2420
- https://doi.org/10.1071/ch9742413
Abstract
Detosylations of derivatives of methyl 12-toluene-p- sulphonyloxypodocarpa-8,11,13-trien-19-oate have been investigated using a modified W-7 Raney nickel catalyst. The final steps in a conversion of podocarpic acid (1) into (+)-19-hydroxypodocarp-8(14)-en- 13-one (21), a useful intermediate for synthesis, have been effected.Keywords
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