A tetranickel(ii) macrocyclic complex incorporating five different bridging groups

Abstract
The synthesis and crystal structure of the tetranickel(II) complex [Ni 4 (L 1 )(OH)(MeCO 2 ) 3 (MeCO 2 H)] is reported, where H 4 L 1 is a macrocyclic ligand incorporating thiophenolate, alkoxo and imine donors; the faces of the tetranickel array are differentiated and two of the nickel ions share three monatomic bridges (S,O,O).

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