Synthesis of graft copolymers of acrylic monomers onto amylose. II. Study of the ceric ion behavior
- 25 June 1992
- journal article
- research article
- Published by Wiley in Journal of Applied Polymer Science
- Vol. 45 (6) , 981-986
- https://doi.org/10.1002/app.1992.070450605
Abstract
A study of the ceric ion consumption during graft polymerization of methyl acrylate (MA), ethyl acrylate (EA), ethyl methacrylate (EMA), and butyl methacrylate (BMA) with amylose was carried out. Grafted acrylic polymers were isolated by the acid hydrolysis method. Weight‐average and number‐average molecular weights were determined by gel permeation chromatography (GPC). The number of grafted chains (mmol) ranged from 8.70 × 10−3 to 12.35 × 10−3 for acrylates and from 3.20 × 10−3 to 6.80 × 10−3 for methacrylates. These results were related to others obtained from the ceric ion consumption studies.Keywords
This publication has 6 references indexed in Scilit:
- Aqueous polymerization of methyl methacrylate initiated by the redox system Ce(IV)–isopropyl alcohol. Kinetics and molecular weightJournal of Polymer Science Part A: Polymer Chemistry, 1989
- Study of the ceric ion behavior on the initiation of butyl acrylate polymerization onto amyloseJournal of Polymer Science Part A: Polymer Chemistry, 1987
- Graft polymerization of acrylic monomers onto starch fractions. III. Effect of carbohydrate structureJournal of Polymer Science: Polymer Chemistry Edition, 1984
- Graft polymerization of acrylic monomers onto starch fractions. I. Effect of reaction time on grafting methyl methacrylate onto amyloseJournal of Polymer Science: Polymer Chemistry Edition, 1983
- Relationship between reduction of ceric ion with poly(vinyl alcohol) and graft copolymerizationJournal of Polymer Science Part A-1: Polymer Chemistry, 1969
- Graft polymerization kinetics of acrylamide initiated by ceric nitrate–dextran redox systemsJournal of Polymer Science Part A-1: Polymer Chemistry, 1966