Asymmetric synthesis of sulphinic esters with the sulphur atom as a sole chirality centre
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 547-548
- https://doi.org/10.1039/c39740000547
Abstract
The reaction of sulphinyl chlorides with achiral alcohols in the presence of optically-active tertiary amines has been found, by means of 1H n.m.r. spectroscopy using a chiral europium complex, to give optically-active sulphinates with optical purity up to 45%.Keywords
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