Bidentate Phosphines of Heteroarenes: 4,6‐Bis(diphenylphosphino)dibenzofuran and 4,6‐Bis(diphenylphosphino)dibenzothiophene
- 1 August 1991
- journal article
- research article
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 124 (8) , 1705-1710
- https://doi.org/10.1002/cber.19911240806
Abstract
No abstract availableKeywords
This publication has 24 references indexed in Scilit:
- Sulfur versus 2,3-.eta.2 coordination of benzo[b]thiophene (BT) in Cp'(CO)2Re(BT)Journal of the American Chemical Society, 1991
- Reactions of (pentamethylcyclopentadienyl)(2,5-dimethylthiophene)iridium with iron carbonyls: a new mechanism for thiophene hydrodesulfurizationJournal of the American Chemical Society, 1991
- 1,8-Bis(diphenylphosphino)anthracene and Metal Complexes1)The title compound 4 was synthesized from dipotassium 1,8-anthracenedisulfonate (9) and potassium diphenylphosphide (Ph2PK). On reaction of 4 with nickel(II) chloride and bis-(benzonitrile)palladium(II) chloride, cyclometallation of the C – H bond in anthracene 9-position led to the square-planar chelate complexes 11 and 13, respectively. In the case of the palladium complex 13, the cyclometallated structure was proved by X-ray structure analysis. Treatment with aqueous potassium cyanide did not remove nickel from 11, but converted 11 into 12 by substitution of chloride with cyanide, demonstrating the high stability of these cyclometallated chelate complexes.European Journal of Inorganic Chemistry, 1991
- Structural aspects of thiophene coordination in transition metal complexesCoordination Chemistry Reviews, 1990
- Synthesis and structure of a stable complex featuring an S-bound dibenzothiophene ligand: RuCl2(4-R2PDBT)2 (DBT = dibenzothiophene)Journal of the American Chemical Society, 1984
- DibenzofuransPublished by Elsevier ,1984
- REACTIONS OF CHELATED ORGANOLITHIUM COMPOUNDS*Transactions of the New York Academy of Sciences, 1965
- Some Metalation Reactions in TetrahydrofuranThe Journal of Organic Chemistry, 1958
- Dimetalation of Phenoxathiin and Phenoxathiin-10-dioxide by Organometallic CompoundsJournal of the American Chemical Society, 1956
- Dibenzofuran. V. DimetalationJournal of the American Chemical Society, 1935