Raman-Spektren der Hexaselenidohypodiphosphate des Mg, Ca und Ba

Abstract
The Hexaselenidohypodiphosphates Mg2P2Se6, Ca2P2Se6 and Ba2P2Se6 have been prepared and their Raman spectra recorded. The observed frequencies of Mg2P2Se6 are assigned on the basis of P2Se6 4- units with D3d symmetry, while these of the Ca and Ba compound show symmetry splitting (assignment with C2h symmetry).

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