Nickel Complex Catalyzed Reduction of Imines
- 1 April 1995
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1995 (04) , 419-422
- https://doi.org/10.1055/s-1995-3924
Abstract
The 1:1 complexes formed in situ from nickel(II) acetate and the thiosemicarbazones of ortho-hydroxy aromatic aldehydes catalyze the hydrosilylation of imines. A variety of imines were reduced in good to excellent yields employing two equivalents of a silane such as triethylsilane and 5 mol% of the catalysts.Keywords
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