Oxytetracycline biosynthesis: mode of incorporation of [1-13C,18O2]acetate
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 802-803
- https://doi.org/10.1039/c39850000802
Abstract
The regiospecific locations of [18O2]acetate-derived oxygen substituents of oxytetracycline (1) have been determined using the 13C n.m.r. isotope shift technique and shown to correspond exclusively to those oxygen-bearing carbons which originate biosynthetically from the carboxy group of acetate.Keywords
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