Hydrazinomercuriation of terminal alkynes and 3-alken-1-ynes. Syntheses of hydrazones and 1-amino-1-aza-1,3-dienes
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 121-122
- https://doi.org/10.1039/c39880000121
Abstract
Although hydrazines cannot be directly added to non-activated, terminal acetylenes in the presence of mercury(II) salts, this difficulty was circumvented by treating hydrazines with 1-alkynylmercury trifluoroacetates (2); in this way, several hydrazones (4a–h) and 1-amino-1-aza-1,3-dienes (4i–m) were easily prepared.Keywords
This publication has 0 references indexed in Scilit: