Insertion of vinylsilane into the ruthenium–silicon bond—direct evidence for the non-metallacarbene mechanism of silylalkene disproportionation
- 1 January 1995
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 2003-2004
- https://doi.org/10.1039/c39950002003
Abstract
The reversible insertion of the vinylsilane molecule into the Ru–Si bond occurs in two different ways to give E-1,2-bis(silyl)ethene and 1,1-bis(silyl)ethene which, in combination with the previous experiments by Wakatsuki et al., provides convincing evidence for a non-metallacarbene mechanism of silylalkene disproportionation.Keywords
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