A means by which measurements of the optical properties of crops and soils can be knowledgeably compared from site to site and instrument to instrument is presented in detail. The definition of bidirectional reflectance factor is reviewed and discussed. Procedures for field implementation are illustrated and discussed. Spectral and goniometric properties of laboratory and field reference surfaces and typical environmental subjects serve as a basis for analysis of uncertainties introduced by differing illumination conditions. Results of a comparison of the performance of three spectrometer systems are presented and discussed. It is concluded that intelligent use of the bidirectional reflectance factor technique is an accurate and practical means to obtain the spectral, optical properties of crops and soils needed for advancements in agricultural remote sensing.