Sulphur-bridged complexes involving the ligand 2,2'-dimercaptodiethyl sulphide
- 1 January 1968
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 21 (11) , 2669-2674
- https://doi.org/10.1071/ch9682669
Abstract
The ligand 2,2'-dimercaptodiethyl sulphide has been prepared and complexes formed with divalent Ni, Pd, Pt, Pb, Hg, and Co. In each of these compounds there is a 1 : 1 molar ratio of ligand to metal. Spectral, magnetic, and conductivity measurements for the nickel(11) and palladium(11) compounds are consistent with molecular configurations involving four-coordinate, neutral, sulphur-bridged structures.Keywords
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