Controlled phase separation in La0.5Ca0.5MnO3

A systematic study of phase separation effects in polycrystalline ${\mathrm{La}}_{0.5}{\mathrm{Ca}}_{0.5}{\mathrm{MnO}}_3$ obtained under different thermal treatments is reported. Samples with average grain size ranging from 200 to 1300 nm were studied. Magnetic and electrical measurements show quantitative differences among samples in their low-temperature behavior, indicating that the fraction of the ferromagnetic (FM) phase gradually decreases as the grain size increases. Percolation of the FM phase in samples with a small fraction of this phase suggests that grain boundaries play a distinctive role in the spatial distribution of coexisting phases. The defective structure at the grain surface could explain the local inhibition of the antiferromagnetic charge ordered phase, an effect that is gradually removed with increasing grain size. Qualitative agreement of the data with this description is found. This effect is also found to be highly dependent on the oxygen content of the samples and its spatial distribution.