Rydberg states of SiF between 42000 and 50000 cm-1

Abstract
Seven Rydberg electronic states of SiF have been observed in the energy range 42000 to 50000 cm-1. Five of them, three 2 Sigma + and two 2 Pi , have never been reported before. They have been rotationally analysed and, for the two states already known, C'2 Pi and D'2 Pi , the rotational analysis has been appreciably extended.

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