Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex

1 January 1982

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 23,p. 1357-1358
https://doi.org/10.1039/c39820001357

Abstract

A stable cis-hydridopentenoylrhodium(III) trimethylphosphine complex, isolated from oxidative addition of pent-4-enal to RhCl(PMe₃)₃, undergoes intramolecular hydroacylation to cyclopentanone.

Keywords

INTRAMOLECULAR HYDROACYLATION
DIRECT OBSERVATION
TRIMETHYLPHOSPHINE
PME3
RHCL
HYDRIDOPENTENOYLRHODIUM
ENAL

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