Rates of reaction of atomic oxygen. III. Spiropentane, cyclopentane, cyclohexane, and cycloheptane
- 1 March 1972
- journal article
- Published by National Institute of Standards and Technology (NIST) in Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry
- Vol. 76A (2) , 77-80
- https://doi.org/10.6028/jres.076a.009
Abstract
Rate constants have been measured from 307 to 652 K for the reactions of atomic oxygen (O3P) with spiropentane, cyclopentane, cyclohexane, and cycloheptane. The derived Arrhenius parameters are k(sp - C5H8) = 1013.60±0.10 exp[(-2890 ± 100)/T], k(cy - C5H10) = 1014.10±0.09 exp[(-2210 ± 100)/T], k(cy - C6H12) = 1014.35±0.09 exp[(-2350 ± 100)/T], and (cy - C7H14) = 1014.46±0.13 exp[(-2230 ± 100)/T] all in units of cm3 mol-1 s-1.Keywords
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