Dense energetic compounds of C, H, N, and O atoms. III. 5‐[4‐nitro‐(1,2,5)oxadiazolyl]‐5H‐[1,2,3]triazolo[4,5‐c][1,2,5]oxadiazole
- 1 October 1993
- journal article
- research article
- Published by Wiley in Heteroatom Chemistry
- Vol. 4 (5) , 521-524
- https://doi.org/10.1002/hc.520040519
Abstract
Diazidoazofurazan 8 was obtained from the bis‐diazonium salt of diaminoazofurazan 7 by treatment with sodium azide and underwent thermolysis to 5‐[4‐azido‐(1,2,5)oxadiazolyl]‐5H‐[1,2,3]triazolo[4,5‐c][1,2,5] oxadiazole 5. The corresponding amine 13 was obtained from the azide 5 by reduction with stannous chloride and was oxidized by ammonium persulfate to 5‐[4‐nitro‐(1,2,5)oxadiazolyl]‐5H‐[1,2,3]triazolo[4,5‐c][1,2,5]oxadiazole 1. The azide 5 was converted to a phosphinimine 9 in a reaction with triphenylphosphine.Keywords
This publication has 12 references indexed in Scilit:
- 2,6‐Dithiodecahydro‐1H,5H‐Diimidazo[4,5,‐b:4′,5′‐e]Pyrazine and related dioxo‐ and diimino‐decahydrodiimidazopyrazinesHeteroatom Chemistry, 1993
- Dense compounds of C, H, N, and O atoms: II [1]. Nitramine and nitrosamine derivatives of 2‐oxo‐ and 2‐iminooctahydroimidazo‐[4,5‐d]imidazoleHeteroatom Chemistry, 1991
- Facile synthesis and nitration of cis-syn-cis-2,6-dioxodecahydro-1H,5H-diimidazo[4,5-b:4',5'-e]pyrazineThe Journal of Organic Chemistry, 1991
- Dense compounds of C, H, N, and O atoms: Nitramine derivatives of diimino- and dioxodecahydro-1h,5h-diimidazo-[4,5-b:4?,5?-e]pyrazineHeteroatom Chemistry, 1991
- Polycyclic Amine ChemistryPublished by Elsevier ,1991
- Calculated structures, relative energies and electrostatic potentials of some tetraaza cyclic systemsStructural Chemistry, 1990
- Chemistry of 1,2,5-thiadiazoles. III. [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazoleThe Journal of Organic Chemistry, 1975
- Preparations and Properties of 5-Phenyl-5H[1,2,3]-triazolo[4,5-c][1,2,5]-oxadiazole, -thiadiazole, and -selenadiazoleBulletin of the Chemical Society of Japan, 1974
- Aromatic azapentalenes. I. Dibenzo-1,3a,4,6a-tetraazapentalene and dibenzo-1,3a,6,6a-tetraazapentalene. New heteroaromatic systemsJournal of the American Chemical Society, 1967
- Interaction of Metal Ions with Amidoximes1aJournal of the American Chemical Society, 1959