Reaction of hydroperoxides with trans-IrX(CO)L2 complexes
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1074-1075
- https://doi.org/10.1039/c39720001074
Abstract
The novel compounds IrX(OOBut)2(CO)L2(X = Cl; L = PPh3, AsPh3, or PPh2Me, and X = Br; L = PPh3 or AsPh3) and IrX(OOCPhMe2)2(CO)(PPh3)2(X = Cl or Br) have been isolated from the reactions of ButOOH or PhMe2COOH with the respective trans-IrX(CO)L2 complexes; the similar reaction of ButOOH with trans-IrI(CO)(PPh3)2 yields IrI2(OOBut)(CO)(PPh3)2.Keywords
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