Trimethylsilyl Chloride-Tin(II) Chloride-Anisole: A Novel Selectivep-Methoxybenzyl Ether Cleavage Reagent

1 January 1992

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1992 (05) , 415-416
https://doi.org/10.1055/s-1992-21364

Abstract

A combination system of trimethylsilyl chloride, anisole, and a catalytic amount of tin(II) chloride cleaved p-methoxybenzyl ethers selectively in the presence of benzyl ethers under mild conditions to afford parent alcohols in high yields.

Keywords

CLEAVAGE REAGENT
CHLORIDE ANISOLE
EM CLASS
CATALYTIC AMOUNT
AFFORD PARENT
COMBINATION SYSTEM
ETHERS SELECTIVELY

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