Differentiation of bacteriochlorin and isobacteriochlorin formation by metallation. High yield synthesis of porphyrindiones via OsO4 oxidation
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1213-1215
- https://doi.org/10.1039/c39860001213
Abstract
Zinc oxochlorins (porphyrinones) react with osmium tetroxide to give exclusively adjacent-ring saturated isobacteriochlorins without any bacteriochlorins that would normally arise from such a reaction with free base porphyrinones; the diols can be converted into the baem d1-like porphyrindiones.Keywords
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