α-Secondary Dialkylallylamines from Aminonitriles via the Bruylants Reaction
- 1 January 1985
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1985 (08) , 743-748
- https://doi.org/10.1055/s-1985-31330
Abstract
The pracitally unknown α-secondary allylamines 1 have been synthesised in good to very good yields by reaction of allylaminonitriles 7 with Grignard reagents. The reaction is regio- and stereoselective and can also be run with α-aminonitriles 9 and vinyl Grignard reagents.Keywords
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