Palladium-catalysed carbonyl allylation by isoprene via regioselective 1,4-addition of tin hydride formed in situ
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 1451-1452
- https://doi.org/10.1039/c39940001451
Abstract
Isoprene reacts with aldehydes in the presence of a catalytic amount of Pd(OAc)2–4PPh3 or Pd(PPh3)4 and a stoichiometric amount of SnCl2 at 40–50 °C in AcOH–H2O to produce 1-substituted 2,2-dimethyl-3-buten-1-ols regioselectively.Keywords
This publication has 0 references indexed in Scilit: