Conversion of non-terminal alkenes into secondary alkyl t-butyl peroxides by peroxymercuriation and reduction with tributyltin hydride
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1117-1118
- https://doi.org/10.1039/c39810001117
Abstract
S-Butyl, 3-hexyl, cyclopentyl, and cyclohexyl t-butyl peroxides have been prepared in yields of 63, 24, 59, and 61%, respectively, by reducing with tributyltin hydride the peroxymercurials derived from the corresponding symmetrical alkenes.Keywords
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