The β-effect of silicon in the orthogonal geometry
- 1 August 1996
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 521 (1-2) , 203-210
- https://doi.org/10.1016/0022-328x(96)06228-6
Abstract
No abstract availableKeywords
This publication has 17 references indexed in Scilit:
- The question of vertical or nonvertical participation of silicon .beta. to a cation in the antiperiplanar stereochemistryJournal of the American Chemical Society, 1993
- .beta. Effect of silicon in the synperiplanar geometryJournal of the American Chemical Society, 1990
- Tetrahedron report number 273Tetrahedron, 1990
- Ab initio investigations of the .beta.-silicon effect on alkyl and cyclopropyl carbenium ions and radicalsJournal of the American Chemical Society, 1989
- Stabilization of positive charge by .beta.-siliconJournal of the American Chemical Society, 1987
- Magnitude and origin of the .beta.-silicon effect on carbenium ionsJournal of the American Chemical Society, 1985
- Dienophilic properties of phenyl vinyl sulfone and trans-1-(phenylsulfonyl)-2-(trimethylsilyl)ethylene. Their utilization as synthons for ethylene, 1-alkenes, acetylene, and monosubstituted alkynes in the construction of functionalized six-membered rings via [4 + 2] .pi. cycloaddition methodologyThe Journal of Organic Chemistry, 1983
- Use of protected .beta.-bromocyclopentenones and .beta.-bromocyclohexenones as .beta.-acylvinyl anion equivalentsThe Journal of Organic Chemistry, 1982
- Deoxymetalation reactions.the mechanisms of deoxysilylation of mono-trimethylsilyl-and bis-trimethylsilyl-substituted alcohols and a comparison to the mechanism of deoxystannylation and deoxyplumbylationJournal of Organometallic Chemistry, 1981
- Reaction of ninhydrin with cytosine derivativesJournal of the American Chemical Society, 1968