Convenient preparations of racemic and enantiopure methyl 6-oxopipecolate
- 1 February 1996
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 26 (4) , 687-696
- https://doi.org/10.1080/00397919608086742
Abstract
Short, convenient syntheses of racemic and enantiopure methyl 6-oxopipecolate are described, starting from either pipecolic acid or (S)-lysine respectively. The sequence for the latter compound relies upon improved methodology for the oxidation of C-6 of lysine.Keywords
This publication has 38 references indexed in Scilit:
- A new concise stereoselective total synthesis of (+)-azimic acidTetrahedron, 1993
- A conjunctive approach to the synthesis of functionalized piperidines from iminesTetrahedron Letters, 1993
- An enantiospecific synthesis of solenopsin ATetrahedron Letters, 1993
- New members of the chiral pool: β-Hydroxypiperidine carboxylates from Baker's yeast reductions of the corresponding keto-estersTetrahedron: Asymmetry, 1993
- .alpha.-Lithioamine synthetic equivalents: syntheses of diastereoisomers from Boc derivatives of cyclic aminesThe Journal of Organic Chemistry, 1993
- A new approach to piperidine alkaloids: an enantioselective total synthesis of (2S,6R)- and (2R,6S)-dihydropinidineJournal of the Chemical Society, Perkin Transactions 1, 1993
- Pyrrolidine, piperidine, and pyridine alkaloidsNatural Product Reports, 1990
- An asymmetric synthesis of chiral 4,4-disubstituted cyclohexenones in high enantiomeric purityThe Journal of Organic Chemistry, 1986
- Chemicals from the glands of antsChemical Society Reviews, 1984
- Synthesis of 2,6-disubstituted piperidines, oxanes, and thianesChemical Reviews, 1983