TiC as a diffusion barrier between Al and CoSi2

Abstract
The stability of the reactively sputtered titanium carbide film sandwiched between cobalt disilicide and aluminum has been studied using Rutherford backscattering, Auger electron spectroscopy, x-ray diffraction, Nomarski optical and transmission electron microscopy. The titanium carbide film is an excellent diffusion barrier through heat treatments at temperatures up to 450 °C for an anneal time of 30 min. The barrier breaks down at 500 °C. Co2Al9 and Ti7Al5Si12 compounds were formed when annealed at 550 °C.

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