Conformational analysis of N-[3,4-dihydro-4-oxoquinazolin-3-yl]aziridines
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 458-459
- https://doi.org/10.1039/c39870000458
Abstract
The X-ray crystal structure of the aziridine (7a) shows that the preferred orientation around the N–N bond has the lone pairs of electrons on adjacent nitrogens eclipsed; the rotamer equilibria around the N–N bonds in the two stereoisomers (7a) and (7b) suggest that this is also the preferred conformation for these substituted hydrazines in solution.Keywords
This publication has 0 references indexed in Scilit: