Conformation of 1,2,6-cyclononatriene

1 January 1975

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 23,p. 927
https://doi.org/10.1039/c39750000927

Abstract

1,2,6-Cyclononatriene is shown by ¹³C n.m.r. to exist in an unsymmetrical twist-boat-chair conformation that can undergo a hindered pseudorotation (barrier height of 12.9 kcal mol^–1) to achieve a C₂ time-averaged symmetry.

Keywords

CONFORMATION
CYCLONONATRIENE
13C
SYMMETRY
UNSYMMETRICAL
MOL
PSEUDOROTATION
N.M.R
HINDERED

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