Cation Distribution and Defect Chemistry of Iron‐Aluminate Spinels
- 1 February 1981
- journal article
- Published by Wiley in Journal of the American Ceramic Society
- Vol. 64 (2) , 86-90
- https://doi.org/10.1111/j.1151-2916.1981.tb09582.x
Abstract
A model describing cation distribution and defect concentrations in iron‐aluminate spinels is presented. Cation distribution equilibrium constants are derived from phase‐boundary data at 1500° and 1280°C. Estimations of the defect concentrations for the entire solid solution are possible using defect equilibrium constants for Fe3O4.Keywords
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