Structure and Reactivity of Early−Late Heterobimetallic Complexes
- 18 November 1999
- journal article
- Published by American Chemical Society (ACS) in Chemical Reviews
- Vol. 99 (12) , 3379-3420
- https://doi.org/10.1021/cr980325m
Abstract
No abstract availableThis publication has 100 references indexed in Scilit:
- Heterobimetallische Komplexe mit 2-(Dimethylaminomethyl)ferrocenyl-LigandenAdvanced Synthesis & Catalysis, 1998
- Metal-support interaction: A theoretical approachJournal of Molecular Catalysis A: Chemical, 1997
- New bimetallic rhodium-zirconium catalysts for homogeneous olefin hydroformylationJournal of Molecular Catalysis A: Chemical, 1996
- Über 2‐(Dimethylaminomethyl)ferrocenyl‐Verbindungen des Vanadiums, Niobs und TantalsZeitschrift für anorganische und allgemeine Chemie, 1994
- Electron‐Reservoir Complexes [FeICp(arene)] as Selective Initiators for a Novel Electron Transfer Chain Catalyzed Reaction: General Synthesis of Fulvalene‐Bridged Homo‐ and Heterodinuclear ZwitterionsAngewandte Chemie International Edition in English, 1994
- Paramagnetic GdIIIFeIII heterobimetallic complexes of DTPA-bis-salicylamideSpectrochimica Acta Part A: Molecular Spectroscopy, 1993
- Kohlenwasserstoffverbrückte Metallkomplexe, XXI Addition von Tetracarbonylosmat und ‐ruthenat an koordinierte ungesättigte Kohlenwasserstoffe: Dreikernige Komplexe mit zwei σ,α‐Allyl‐, Methylallyl‐, Cyclohexadien‐, Cycloheptadien‐, Cyclohexadienyl‐, Cycloheptatrien‐ und „Thiophen”︁‐Brücken Hydrocarbon‐bridged Metal Complexes, XXI. – Addition of Tetracarbonylosmate and ‐ruthenate to Coordinated Unsaturated Hydrocarbons: Trinuclear Complexes with two σ,α‐Allyl, Methylallyl, Cyclohexadiene, Cycloheptadiene, Cyclohexadienyl, Cycloheptatrien, and “Thiophene” Bridges The addition of organometallic nucleophiles [M(CO)4]2‐ (M = Os, Ru) to [(Cp)(ON)(OC)Mo(allyl)]+, [Cp(OC)2Mo(butadiene)]+, [(OC)3Fe(cycloheptadienyl)]+, [(OC)3Fe(cycloheptadienyl)]+, [(OC)3Mn(benzene)]+, [(OC)3Mn(thiophene)]+, [(OC)3‐Mo(cycloheptatrienyl)]+ leads to the heterotrimetallic η1:η2‐, η1:η3‐, η1:η4‐, η1:η5‐, η1:η6‐hydrocarbon‐bridged complexes 1 ‐ 7. The structures of cis‐(OC)4Os[(μ‐η1:η4‐C7H9)Fe(CO)3]2 (4), cis‐(OC)4Os[(μ‐η1:5‐C6H6‐Mn(CO)3]2 (6), and cis‐(OC)4Os‐[μ‐η1:η6‐C7H7‐Mo(CO)3]2 (7b) have been determined by X‐ray analysis. The fluxional behaviour of 6 in solution has been studied in a temperature range from – 70 to +60°C. The comparison of observed and calculated 1H‐NMR data indicates a 1,2‐shift mechanism (ΔG+ = 49 kJ/mol).European Journal of Inorganic Chemistry, 1991
- Kohlenwasserstoffverbrückte Komplexe XX Nucleophile Addition von Carbonylmetallaten an kationische Hexadienyl‐, Cycloheptadienyl‐, Cycloheptadienyl‐ und Cyclooctadienyl‐Komplexe von Eisen und Ruthenium: Heterodimetall‐Komplexe mit η1:η4‐C6‐, ‐C7‐ und ‐C8‐KohlenwasserstoffbrückenEuropean Journal of Inorganic Chemistry, 1991
- Complexation of a Novel Organoytterbium(II) Ligand with Dimethylplatinum(II): Crystal Structure of the Resulting Heterobimetallic ComplexAngewandte Chemie International Edition in English, 1989
- Darstellung und Eigenschaften von und Reaktionen mit metallhaltigen Heterocyclen, LX. Untersuchungen zur Darstellung und Struktur von PhosphidomolybdatenEuropean Journal of Inorganic Chemistry, 1988