Regiospecific Synthesis ofN-Sulfonyl Derivatives of 3,5-Diamino-1H-1, 2,4-triazole and 2,5-Diamino-1,3,4-thiadiazole

Abstract
Condensation of the S,S-dimethyl N-(alkylsulfonyl)carbondithioimidates 1 with aminoguanidine bicarbonate and hydrazinecarbothioamide leads to the regiospecific synthesis of N-sulfonyl derivatives of 3,5-diamino-1H-1,2,4-triazole 2 and 2,5-diamino-1,3,4-thiadiazole 3, respectively.

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