Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation
- 1 October 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (10) , 1007-1009
- https://doi.org/10.1055/s-1996-5634
Abstract
ω-Alkenylbenzyllithiums, bearing a chiral alkoxy group in suitable position cyclise to arylcyclopentanes with very high control of the relative stereochemistry and very high stereofacial differentiation. This reaction has been used in the synthesis of enantiopure arylcyclopentanes derivatives.Keywords
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