C–H bond activation and C–N coupling reactions of methylacetylenes and allenes with an imidotitanium complex
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2555-2556
- https://doi.org/10.1039/a806936k
Abstract
Reaction of an imidotitanium complex, stabilized by a tridentate diamidopyridine ligand, with the methyl acetylenes MeC2Me and MeC2Ph led to C–H-activation of the substrate and subsequent C–N coupling to give azatitana-tetracycles which may be viewed as dimetallated enamines; the same compounds were obtained in reactions with the allenes Me(H)CCCH2 and Ph(H)CCCH2.Keywords
This publication has 0 references indexed in Scilit: