Diastereoselective Synthesis of Metal Carbene-Functionalized Spirocyclic Carbohydrates1
- 1 October 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (10) , 995-996
- https://doi.org/10.1055/s-1996-5641
Abstract
The cycloisomerization of carbohydrate-derived butynols at a low-valent chromium or tungsten template affords spirocyclic 2-oxacyclopentylidene complexes which allow subsequent diastereoselective α-functionalization.Keywords
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