Nucleophilic displacement of methide from silicon. Steric compression of geminal trimethylsilyl groups?
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 774-775
- https://doi.org/10.1039/c39890000774
Abstract
6,6-Bis(trimethylsilyl)norbornan-endo-2-ol (6) undergoes base-induced intramolecular displacement of a Si–Me group with formation of (9), in contrast to the monosilylated analogue (7).Keywords
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