Insertion of methyl isonitrile into niobium- and tantalum-chlorine bonds
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 127b-128
- https://doi.org/10.1039/c3973000127b
Abstract
Methyl isonitrile inserts into the metal-chlorine bond of niobium and tantalum pentachlorides to give [MCI4{C(CI)NMe}(MeNC)](M = Nb or Ta) and [NbCI3{C(CI)NMe}2(CNMe)]; the complex [NbCI3{C-(CI)NMe}2PPh3] has also been prepared.Keywords
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