Equilibrium and Transport Properties of Concentrated Electrolyte Solutions

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Abstract
A historical survey is followed by a discussion of a number of problems associated with concentrated solutions of electrolytes containing two ion constituents: general thermodynamic properties, dissociation equilibria, phase separation, analytical representation of the thermodynamic functions over the entire range of concentrations, and general relationships in electrical conductivity, diffusion, and sedimentation. A number of relationships valid at all concentrations is formulated, and known relationships pertaining to dilute solutions are derived from these as special cases. The discussion of concentrated solutions is illustrated by numerical examples, most of which are based on recent results.