LYCOPODIUM ALKALOIDS: V. THE BROMINATION OF LYCOPODINE AND THE STRUCTURE OF ALKALOID L.20
- 1 March 1963
- journal article
- research article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 41 (3) , 649-657
- https://doi.org/10.1139/v63-092
Abstract
Monobromination of lycopodine hydrobromide in chloroform yields 6α-bromolycopodine hydrobromide, which can be epimerized to 6β-bromolycopodine hydrobromide. Hydrolysis of 6α-bromolycopodine proceeds with overall retention of configuration to give 6 α-hydroxylycopodine, which is identical with the Lycopodium lucidulum alkaloid L.20. On the basis of some of the rotatory dispersion data presented it is suggested that positively charged nitrogen has a negative specific rotativity.This publication has 6 references indexed in Scilit:
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