Spectroscopic studies on the hexafluorides of rhenium, osmium, iridium, and platinum isolated in low-temperature matrices
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 5,p. 1341-1345
- https://doi.org/10.1039/dt9880001341
Abstract
The compounds ReF6, OsF6, IrF6, and PtF6 have been isolated as monomeric species in intert-gas matrices at low temperatures, and characterised by i.r. spectroscopy. Subsequent u.v.–visible studies reveal a complex pattern of electronic absorptions, and a detailed assignment of these in terms of charge transfer, d–d, and intra-configurational transitions is presented.Keywords
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